Program.cs

using System;
using System.Diagnostics;
using System.Runtime.InteropServices;
using System.Windows.Forms;

namespace PrintScreen
{
    class InterceptKeys
    {
        private const int WH_KEYBOARD_LL = 13;
        private const int WM_KEYDOWN = 0x0100;
        private static IntPtr _hookID = IntPtr.Zero;
        private static SelectionFrame _frame = new SelectionFrame();

        [STAThread]
        public static void Main()
        {
            _hookID = SetHook(_hookCallback);
            Application.Run();
            UnhookWindowsHookEx(_hookID);
        }

        private static IntPtr SetHook(LowLevelKeyboardProc proc)
        {
            using (Process curProcess = Process.GetCurrentProcess())
            using (ProcessModule curModule = curProcess.MainModule)
            {
                return SetWindowsHookEx(WH_KEYBOARD_LL, proc, GetModuleHandle(curModule.ModuleName), 0);
            }
        }

        private delegate IntPtr LowLevelKeyboardProc(int nCode, IntPtr wParam, IntPtr lParam);

        private static LowLevelKeyboardProc _hookCallback = HookCallback;
        private static IntPtr HookCallback(int nCode, IntPtr wParam, IntPtr lParam)
        {
            if (nCode >= 0 && wParam == (IntPtr)WM_KEYDOWN && (Keys)Marshal.ReadInt32(lParam) == Keys.PrintScreen)
            {
                _frame.Show();
            }

            return CallNextHookEx(_hookID, nCode, wParam, lParam);
        }

        [DllImport("user32.dll", CharSet = CharSet.Auto, SetLastError = true)]
        private static extern IntPtr SetWindowsHookEx(int idHook, LowLevelKeyboardProc lpfn, IntPtr hMod, uint dwThreadId);

        [DllImport("user32.dll", CharSet = CharSet.Auto, SetLastError = true)]
        [return: MarshalAs(UnmanagedType.Bool)]
        private static extern bool UnhookWindowsHookEx(IntPtr hhk);

        [DllImport("user32.dll", CharSet = CharSet.Auto, SetLastError = true)]
        private static extern IntPtr CallNextHookEx(IntPtr hhk, int nCode, IntPtr wParam, IntPtr lParam);

        [DllImport("kernel32.dll", CharSet = CharSet.Auto, SetLastError = true)]
        private static extern IntPtr GetModuleHandle(string lpModuleName);
    }
}