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AEEW-R956.txt
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T Na
AEEW - R 956 =~~~
NOT-FOR-PUBLICATION (Commercial)
Safeguard this document as directed overleaf
UNITED KINGDOM ATOMIC ENERGY AUTHORITY
Reactor Group
AN ASSESSMENT OF A 2500 MWe MOLTEN
N . CHLORIDE SALT FAST REACTOR
EDITED BY:
J SMITH
W E SIMMONS
CONTRIBUTORS:
DR R C ASHER, AERE
DR G LONG, AERE
DR H A C MCKAY, AERE
DR D L REED
Technical Assessments and Studies Division
Atomic Energy Establishment, Winfrith, Dorchester, Dorset, 1974
NOT 1POR PUBLICATION (COMMERCTAL)
AEEW-R 956
AN ASSESSMENT OF A 2500 MWe MOLTEN
CHLORIDE SALT FAST HEACTOR
Edited by J Smith
and
W E Simmons
Contributors:
Technical Assessments
and Studies Division,
AEE Winfrith
Dr
Dr
Dr
Dr
R C Asher, AERE
G Long, AERE
H A C McKay, AERE
D L Reed, AEE
August 1974
In the 1interest of paper
W 10774 economy this document has
been printed to a reduced
standard.
= Nl
1
NOT FOR_PUBLICATION (COMMERCIAL)
CONTENTS
INTRODUCTION
MSFR CONCEPTS
CHEMICAL ASPECTS OF THE FUEL
REACTOR PHYSICS
SAFETY AND OPERATIONAL ASPECTS
5.1 Normal Operation
5.1.1 Startup
5.1.2 Power Control
5.1.3 Hotspots
5.1.4 Shutdown
5.1.5 Small Leakages
5.2 Fault Conditions
ENGINEERING DESIGN PHILOSOPHY
.1 Choice of Materials
Fuel Inventory
Choice of Intermediate Coolant
Choice of Power Plant
Blanket Inventory and Cooling
Reliability and Maintenance
o O O O O O Ov
Oy W S\ no
.{ Engineering Development
OUTLINE SYSTEM DESIGNS AND AUXILIARY PLANT
7.1 General Aspects
7.2 The Indirectly Cooled Concept
7.3 Design Variations of the Indirectly
Cooled Concept
7.4 Special Auxiliary Plant
7.5 PFilling, Draining and Dump Systems
il
Prgne No
N =W
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25
NOT FOR PUBLICATION (COMMERCIAL)
CONTENTS Page No
V.00 lmerpeney Cooling System 20
7.7 Salt Cleanup and Gaseous Fission 20
Product Removal
7.8 Processing Plant 28
7.9 Remaining Plant 28
7.9.1 Containment 28
7.9.2 Preheating 29
7.9.5 Shielding 29
7.9.4 Pumps 29
7.9.5 Steam Plant 29
8. MATERIALS 50
9. COSTS 32
9.1 Capital Costs 32
9.2 Fuel Costs 33
9.3 Overall Generating Costs 35
10. CONCTHUITON 35
11. PARAMETERS FOR TNDIRECT AND DIRECT COOLED VERSIONS 37
OF A MOLTEN SALT FAST REACTOR - SUMMARY
REFERENCES 45
ACKNOWLEDGEMENTS 46
APPENDIX I b7
IT 53
iii
4,
no
la
1b
Y
4p
NOT FOR PUBLICATION (COMMERCIAL)
TABLES
COMPARISON OF PERFORMANCE OFF REFERENCE
MOPR WITH OTHER FAST REACTORS
2500 MW(e) NET MSIFR: SUMMARY OF FEATURES
MSEFR DIRECT LFAD.CURTAIN COOLED SYSTEM - PARAMETERS
NUCLEAR PERIFORMANCE OF A PRELIMINARY UKAEA DESIGN
Ol AN INTERNALLY COOLED 6000 MW(t) MSFR USING
CL37 SALT
MSFR INTiERNALLY COOLED DESIGN PARAMETERS
FIGURES
DESIGN 1. INDIRECTLY COOLED MSFR - LEAD COOLANT
Pafe No
10
22
49
56
57
ALTERNATIVE DESIGNS FOR INTERMEDIATE HEAT EXCHANGERS
FOR LOW CONDUCTIVITY FUEL SALT
DESIGMN 2. TNDIRECTLY COOLED MSFR - LEAD COOLED WITH
ALTERNATIVE CORE AND INTERMEDIATE HEAT EXCHANGER
LAYOU'L.
DESIGN 5. INDIRECTLY COOLED MSFR - PRELIMINARY DESIGN
O HELIUM COOLED VERSION.
DESIGN 4. DIRECT COOLED MSFR WITH JET PUMP ASSISTLD
CIRCULATION
SIMPLIFIED DIAGRAM OF DIRECT SYSTEM SHOWING LEAD
CURTAIN AND POLOIDAL FLOW
GENERAL VIEW OF 2500 MWe MSFR (INDIRECT SYSTEM BASED
ON DE3IGN 1)
6 &7 MSFR RBUIILDING LAYOUT (BASED ON DESIGN 1)
8
9
10
11
12
SIZE COMPARISON OF MSKFR WITH CFR AND MSBR
FLOW DIAGRAM -~ INDIRECT SYSTEM
"I,OW DIAGRAM-I'UEL AND BLANKET SALT CLEANUP AND OFF-
GASSING
FLOW DIAGRAM - DIRECT SYSTEM
INTERNALLY COOLED MSKFR
iv
NOT FOR PUBLICATION (COMMERCIAL)
1. Introduction
As a result of some initial studies in 1964 and 1965,
it was concluded that the line of investigation of most interest
to the UK on molten salt reactors and which would also be
¢ omplementary to the US investigations would be on a fast reactor
version. A preliminary study of a fast system using the U233%/Th
cycle and fluoride salts did not indicate encouraging results and
it was therefore decided that a Pu/U238 cycle would be examined.
This 1nvolved the use of chloride salts and work on salt chemistry
began in 1965 which in 1970 was extended to include additional
materials aspects, The assessment and fluid flow study work was
carried out mainly in 1971 and 1972. This report presents an
overall summary. It is in the nature of a survey report as the
limited effort available has meant that the depth to which questions
could be investigated has been restricted.
The initial question which is bound to be asked is why
consider a fluid fuel, with all the implications of a highly
active circuit If it is considered that the ultimate refine-
ment of the solid fuel system will appear as some form of fast
reactor, then to make further progress beyond this, some basic
change 1n concept has to be made, and it seems clear that the
most fundamental would be to escape from the trammels of fuel
fabrication with fine tolerances, expensive active transport
and also from central processing if suitable on-line methods
can be developed to treat the fuel directly.
A basic safety feature, in principle, is that a fluid
fuel can be disposed of from the reactor to ever-safe containers,
while good negative temperature coefficlents should limit
excursions and potentially offer a self-regulating system. The
current feasibllity studies have sought to demonstrate how far
these potentialities might be realised and to give a preliminary
appraisal of the economic and performance prospects. The table
below summari ses the possible advantages and disadvantages which
have become apparent as the investigations have been in progress,
and it is hoped this will form a useful reference against which
to judge the success achieved to date.
Table I - Advantages and Disadvantages of Molten Salt Fast
Reactors (MSFRs)
I. Potential Advantages
1. No loss of neutrons occurs in fuel cladding or
structural material in core,
2. Continuous addition or removal of fuel is possible
under power,
3. Simple control of power may be achievable by coolant
conditions and power demand. It seems possible to
avoid control rods or equivalent systems.
NOT IPOR PUBLICATION (COMMISKCEAL)
b, Strong negative temperature coefficient gilves
basic safety.
5. High heat capacity of fuel restricts temperature
rise on loss of normal cooling. A dump system
with independent cooling system can be used for
decay heat removal,
6. Reactor vessel is small. Prefabrication of the
vessel at works should be possible, thus reducing
construction time and interest charges. In the
event of a fault in the vessel fuel may be removed
and the vessel size is such that its replacement
can be contemplated.
7. Building layout is compact due to the small size
of the reactor vessel and primary circuit and
absence of elaborate fuel handling route.
8. The system can basically be at low pressure apart
from pumping pressures.
9. Fuel handling by pumps and pipework should be a
simpler operation than solid fuel handling.
10. The system is sulted to on-site close coupled fuel
processing.
11. A substantial proportion of the fission products
can be continuously removed by a close coupled
process.
12, Savings in fuel element fabrication and development
costs seem possible,
—
13. Potentilal for high temperatures and higher cycle
efficiency 1s good.
Disadvantages
1. Higher fuel inventory than in LMFBRs is required
to give heat transfer and transport.
2. Molten salt fuel has relatively poor heat transfer
characteristics compared with sodium.
3. The high melting point of suitable fuel salts (v5E0 )
involves pre-heating, and heating to prevent freezin®
during prolonged shutdowns. The femperatures involv~d
prevent access to plant.
b, The high melting point of the fuel salt also 1mposes
an additional constraint on heat exchanger systems in
order to prevent salt freezing on heat transfer
surfaces 1f low return salt temperatures are
employed, especially i high heat transfer rates
apply on the coolant side.
2
NOT FOR PUBLICATION (COMMERCTAL)
5. Fresence of fission products in the fuel salt - a
hhimh standard of plant reliability and lenk
t,irhtness with remote maintenance i1is required,
6. Limitation of choice of materials of construction
due to corrosion and high temperature,
2. MSFR Concepts
In the main part of this report two versions of the MSFR are
considered, which have been designated as the Direct Cooled and
the Indirect Cooled systems., Figures la and 1lb illustrate the
second of these, where the fuel salt is pumped through a core
vessel of dimensions which permit criticality and in which the
fission heat is generated. It then flows through heat exchangers
on the secondary side of which is circulated a coolant which
transfers the heat to the steam generators. This is the classical
pattern of fluid fuel designs and was the form originally
considered. However, the investigations at that time considered
the circuit hold up and fuel inventory for the layouts examined
to be too high and an alternative was sought, emanating from a
suggestion by Bettis of ORNL,
In this, the Direct Cooled version (See Figures la and Ub),
the salt is both cooled and circulated within the core vessel
(in what is known as poloidal flow) by a curtain of lead drops
injected down the periphery of the vessel. This in principle
gives low fuel hold up because no external inventory except
that for auxiliary circuits is required. The investigations on
this type have focussed on materials aspects and operating
conditions, and importantly also, the nuclear and thermal
performance, In the course of the study of heat transfer and
fluid flow features, it became apparent that there could be
substantial limitations on the heat removal capability of the
direct scheme, and further problems in achieving the necessary
separation of lead and salt at the region where the lead must
pass out of the core vessel to the heat exchangers,
For this reason, the Indirect system has been re-examined
in the later part of the study, and appears to be of considerable
interest, provided that the compact layouts and high heat exchanger
volumetric ratings now postulated can be achieved in practice, thus
giving a reasonable fuel inventory. The main emphasis in this
report is concerned with this latest Indirect version, while details
of the Direct system are given in Appendix I.
During the course of this work, a report by Taube (1) became
available which suggested a further alternative in which the heat is
r emoved from the core salt by a heat exchanger system within the
core., The coolant is a salt of the same composition as the blandket
salt. A preliminary appraisal of this scheme is given in Appendix
IT.
The reactor cases studied have all been of 6000 MW thermal
output. This (equivalent to about 2500 MWe) was chosen as typical
of the size of the unit in a large grid system in the later part
of the century.
NOT TPOR PUBLTICATION (COMMERCTAL)
3. Chemical Aspects of the Fuel
The concept of employing a molten salt as the combined
fuel and primary cooclant of a nuclear reactor presents many
novel problems in both reactor design and system chemistry.
The achievements of the ORNL Molten Salt Reactor Programme
both give confidence in the feasibility of a molten salt
concept and lend support to the view that in many important
chemical respects a molten salt system can be regarded as
being in a state of chemical equilibrium. Much progress
can then be made by considering the various equilibria which
might occur both within the salt and between the salt and
its environment, particularly since many of the equilibria
involved are predictable, at least in broad outline.
When selecting a salt mixture for use in the core and
blanket of the NSFR many factors, chemical and nuclear, must
be taken into account. The reference core salt NaCl:UCl,:PuCl
containing in the region ofr 30 to 40 mole % of heavy atoés
(50 to 55 welght?) fulgils the relevant criteria, including
melting point (550~5807C), nuclear properties and chemical
stability. Should occasion demand, variations are possible
without detracting from its essential properties as a fuel
by replacing some or all of the sodium chloride with potassium,
magnesium or calcium chlorides.
5
For the feasibility of the concept it is essential that
under all 1likely conditions throughout the 1life of the reactor
the core and blanket salts should, firstly, be compatible with
the container materials and secondly, should nct undergo
reactions which bring about precipitation, especially of the
plutonium, within the reactor. Compatibility is achieved in
the initially pure fuel salt by ensuring that materials for
the containment are selected from those which form relatively
unstable chlorides, such as iron, nickel and the refractory
metals. Since the chlorides in the fuel salt are of high
stability little reaction with these metals 1s then expected,
and this 1s borne out by experiment. During reactor operation
additional chemical species are introduced into the salt and
processes are envisaged in order to maintain their concentra-
tions at some acceptable equilibrium level, Of the important
fission products, some are gaseous and can be removed
¢ ontinuously, some, notably Rb, Cs, Sr, Ba, Zr and rare
earths, farm chlorides and remain the salt while others,
notably Mo, Ru and Pd are unstable as chlorides and will
precipitate from the salt as metals. Experience in the MSRE
suggests that these will in part be discharged as a fog with
the 1inert gases and partly plate out on metal surfaces. In a
d irect cooled system an additional possibility is dissoclution
in the lead coolant.
While it is possible that certain individual fission products
might take part specific corrosion reactions, as chemical
entities the majority of fission products should not significantly
modify the corrosion behaviour of the salt and their concentra-
tion will be maintained at a level acceptable to neutron economy
by chemical reprocessing.
NOT TOR PUBLICATION (COMMERCIAL)
During fission, however, there is mis-match between the number
of chlorine atoms avallable from the fissioned chloride and the
number taken up by the fission products. The excess chlorine
produced reacts with the strongest reducing agent present,
UCl,, forming UCl In the pure form this is highly corrosive,
but’predlotlon anfi experiment both show that when UCl, is
dissolved in fuel salt at low concentrations little a%tack of
c ontainer metals is to be expected, The concentration of UCl
is readily maintained at acceptably low levels by reacting the
fuel salt at a modest rate with, for example, metallic uranium.
By a similar argument, supported by ORNL irradiations of
fluoride fuel sats at comparable heat ratings, UCl, is expected
to react rapidly with any short-lived oxidising spécies produced
under the intense fission fragment irradiation of the salt.
Neither evolution of chlorine from the melt nor enhanced attack
of the container materials under irradiation are therefore to be
expected.
Other specific chemical spec1es which are of interest in
comޤt1b111+y will be gresent in the melt. The (n,p) reaction
Cl will produoe S at a mean concentration (up to a few
thousand ppm in the salt) which depends upon the fuel rating and
the isotopic concentration of the chlorine, Account must also
be taken of the effect of introducing oxide into the melt by
1ngress of air or water vapour. The UCl, component of the fuel
is expected to combine with both the sulahur and the oxygen and
so reduce their reactivity towards structural materials,
Experimental verification of this point is required, particularly
for such materials as nickel which are knwon to be susceptible
to sulphur attack.
Consideration of the stability of corrosion product chlorides,
backed by 1aboratory experience, lead to the conclusion that
alloys based on iron, nickel and the refractory metals such as
molybdenum will be compatlble with chloride fuel and blanket
salts in which the UCl, contents is maintained at a low level,
less than a few peroen% of the UCl, content. More reactive
metals such as chromium could 1n aédltlon be admitted as minor
constituents in an alloy provided some surface leaching were
allowed for. When lead is also present, as in the direct cooled
system, the lead itself is compatible with fuel salt, but the
choice of container material is more restricted. Nickel alloys
are excluded, while only a limited range of iron alloys is
possible. The presently preferred container for the two liquids
together is molybdenum, either as bulk material or in the form
of a protective clad on an iron-based structure.
The fission process produces chemical species which might
lead to precipitation of components from the fuel salt. These
include fission products reacting to give complex chlor%ges
(e.g. Cs,.UCl,) or specific ompounds (e.g. UI,) and the
forming %ulpgldes (US). Although not all the relevant solubilities
are known it is likely that uranium compounds will precipitate
in preference to the corresponding plutonium compounds.
Preliminary measurements have conflrmeotmat the material precilpitated
from a fuel salt containing both uranium and plutonium is largely
uranium sulphide.
NOT T"OR PUBLICATION (COMMERCTAL)
The solubility of sulphur, however, is much less than the amount
estimated to be formed in a natural-chlorine fuelled systom.
A low solubillity of sulphur, or of any of the other uranium-
bearing species, would not adversely affect the feasibility of
t he system. DBy a simple process - such as adjustment of temper-
ature and UCl, content - precipitation could be induced in a
C Lean=-up circdit. Since the species concerned are being produced
at a predictable rate the concentrations in the core could be
safely maintained close to saturation and even an inefficient
removal process would suffice. By contrast the adventitious
admission of oxygen is likely to be unpredictable. It is there-
fore necessary firstly to ensure that the fuel salt is capable
of dissolving the amounts of oxygen which might conceivably be
admitted and secondly to keep the normal oxygen content of the
melt well below the saturation level, so maintaining the capacity
of the melt to dissolve additional oxygen. Measurements of the
oxide solubility have demonstrated an adequate capacity for
dissolving oxide, but have also shown that only a small decrease
in solubility can be expected when conditions are changed from
those normnally obtaining in the reactor. The required degree
of oxygen removal is therefore not possivle by, for example,
simple adjustment of the temperature, and alternative chemical
methods have been sought. Precipitation of oxygen as alumina
by reaction with aluminium, introduced into the salt as the
liquid sodium chloraluminate, has been studied in some detail.
This reaction promises to provide not only an efficient method
of oxide removal but also a convenient means of converting
uranium and plutonium oxides produced in the reprocessing cycle
into fuel or blanket salt., In further tests the prediction
that from melts containing both UCl3 and PUCl. uranium is
precipitated as oxide in preference-to pluton%um has been
confirmed over a range of relevant conditions.
In addlition to the adjustment of the chemistry of the fuel
and blanket salts on a fairly rapid cycle as just described
(which will, incidentally, also serve to remove any inert gac
fisslon products not removed in the cover gas), and defined
as clean up 1t is necessary to carry out more drastic processes,
probably on a slower cycle defined as processing, whose basic
purpose 1is to remove fission progycts from the core and plutonium
from the blanket. If separated Cl is used, this must be recycled
without appreciable loss; and may cause prablems in the reconversion
of heavy metal to chlorides when excess chloride is required.
It 1is also desirable to recycle the sodium in the fuel salt to
avold a radiocactive disposal problem.
Two contrasting schemes have been considered to meet these
objectives, one based on mainly well-established aqueous processes
and the other on a series of pyrochemical steps. each of which
has been tested in the laboratory. For the aqueous route it is
necessary to develop processes to convert the reprocessed heavy
atom content to chloride, as well as, probably, to recover the
sodium chloride for recycling. The pyrochemical route uses
a series ol metal displacement reactions in molten chloride
media., The feasibility of such a process has been demonstrated
at ANL on a pilot-plant scale for oxide fuels, but much
engineering development is required to evolve a workable and
reliable process, especially in view of criticality restrictions.
6
NGT FOR PUBLTICATTON (COMMERCTAL)
The process can be operated close-coupled to the reactor and
on a much shorter cycle than the aqueous route, and the plant 1is
comrnct. At the present time there is insufficient information
to make meaninpful cost estimates for this process but the
prel iminary work that has been done indicates that capital and
operating costs may be high because of the small batch type
operations needed,
On the other hand, an aqueous reprocessing plant for high
burnup fuel cannot economically serve much less than 20 GWe
of installed nuclear capacity, although relatively small
additions at the head and tail end could be made to such plant
used for other fast systems.
To summarise, in exploring both theoretically and experiment-
ally the chemistry of molten chlorides as a fast reactor fuel
no practical impediment to their successful application has
been found, potential methods of fission product reprocessing
and salt clean-up have been identified and some specific
reactions of possible future value to the fuel cycle have been
d eveloped.
i, Reactor Physics
An important aim of the reactor physics investigations has
been Lo see what form the proposed reactor of 6000 MW(t) to be
built around Lhe year 2000 would have to take in order to
achieve a doubling time of 15 - 20 years, this figure being
judged against forecast doubling times of the generating
system as a whole.. However, there is not only considerable
uncertainty in this type of forecasting but variation in
r equirements in different countries.
Furthermore, for example, fuel inventory around the turn of
the century may not be such a critical criterion. A range of
alternatives was therefore explored.
Throughout the study only salts containing a mixture of
(U+Pu) Cl. and NaC?2 were considered. Early in the study it
became cléar that for the better ranges of nuclear performance
consideration would have to be given to the use of chlorine
enriched in the C1-37 isotope and it was found necessary to under-
take an evaluation of the cross-section data. For simplicity the
initial calculations assumed full enrichment to Cl-37.
To understand the basic physics performance of the MSFR a
series of calculations with simple spherical reactor systems was
made. The results of this study indicated that:-
(a) 1increase in heavy metal content within the salt improves
the nuclear performance although the salt becomes more
costly and its melting point increases. The composition
recommended as a result of this study was MO%O(U+Pu)
C1./60% NaCl (this has a melting point of 577 C), the Pu
crdction being about 10% of the heavy metal content.
10T PO PUBLICATION (COMMERCTIAL)
(b) acceptnble breeding gains are not obtained over the
rongme of core sizes consistent with satisfactory
fuel ratings unless the core 1s surrounded by a
blanket (initially 40% UCLl./60% NaCl) - that is a
sinpgle-region system did-ngt have adequate performance.
(¢) a blanket thickness of 1lm appeared to give a reasonable
nuclear performance without leading to excessive blanket
salt inventories.
(d) the breeding gain is increased by a factor of two when
natural chlorine is replaced by Cl=37,.
(e) a doubling time* of less than 20 years for the direct
cooled system would be obtained if cor% volumetric
ratings could:ge greater than 270 MW/m- with natural
Cl or ~100 MW/~ with Cl=37 in the salt. For the indirect
system, where a large part of the overall fuel inventory
is in the external heat removal circuit (see Section 6.2
for a discussion of factors controlling this) doubling
times in the region of 20 years can only be achileved
1f the core volume is reduced until the rating is
n360 MW/ m”, as in the designs shown.
(f) the temperature coefficient of reactivity and Doppler
coefficients are large and negative over the range of
operating temperatures considered so giving a means of
reactor control.
Tndirect Cooled MSFR
A lead cooled reactor with a layout as shown in Figure la
was analysed in more detail and with high C1-37 salt the doubling
time is ~25 years and with natural Cl~rUlb years. A simple
analysis showed that the system should be stable to small
reactivity perturbations if the ratio of the core volume to
total volume of core salt was greater than ! and the engineering
studies showed that this requirement eould be met with a margin.
Although it was not possible to carry out more than an elementary
analysis of control arrangements, the limited study suggested
that control of power level could be achieved by varying the
flow rate of salt through the core and heat exchangers, the
temperature of the salt remaining essentially constant at all
power levels due to the combination of the negative temperature
coefficient and the absence of the heat transfer and fuel pin
temperature differentials of a solid-fuel reactor.
The results of the studies of the transient behaviour of
this reactor with a simplified reactor model showed that the
temperature rise of the core salt due to a reactivity step
of up to $1 should be less than 300°C, and for 7 pumps failing
out of 8 will be less than QBOOC. Also the effect of changes in
the fraction of delayed neutrons re-entering the core from
the external circuit with wvariation of primary circuit flow rate
was assessed to be small.
¥ All doubling times quoted make a notional allowance for holdup
in processing plants.
NOT FOR PUBLICATION (COMMERCTAL)
Direct Cooled MSFR
The initial physics studies of this concept (see Figure lda
for the lay%ut) were based on volumetric rating within the core
of 100 MW/m” to conform with the limits on heat removal which
it was then thought might apply. The performance with natural
Cl in the salt was disappointing with a doubling time of ~60
years. To improve the doubling time chlorine was replaced by
high enrichment C1-37 and the doubling time obtalned was between
20 and 24 years depending on the various core-and blanket
configurations studied to accommodate flow requirements., To
give competitive fuel costs in terms of plutonium and C1l-37
inventory, i1t would be necessary to reduce the size of the
reactorzfuch that the volumetric rating substantially exceeded
100 WM/m”., The size eventually chosen for tge referenp%
engineering design has a core volume of 40 m” (150 MW/m
volumetric rating), giving a doubling time, taking account of
full fission product absorption, of about 20 years, which could
be reduced to 18 years if U40% of the fission products are
removed with an on-ine process and there is a low reprocessing
holdup (i.e., for an in-line plant or quick turn round in a
nearby centralised plant). It should however be noted (see
Appendix I) that there are serious doubts about heat removal
and separation at this rating.
In the original design the loss of the curtain of lead drops
(e.g. due to pump failures) increased the reactivity due to
replacement of the lead by the salt., But if the proportionate
volumes of lead and salt within the core are made to remain
constant for all confilgurations of the lead curtain by ensuring
that on loss of flow, the lead remains in a pool at the bottom
of the vessel the reactivity was decreased (8k = - 0.003),
This efg%:%k gogether with a negative temperature coefficient of
-6 x 10 —/ C gives a possible means of reactivity control by
the curtain, An analysis of a series of steady state runs at
power levels over the range of interest showed that it was
possible, by altering the inlet and outlet temperature, to keep
the lead flow constant, thus avoiding the effect of reactivity
changes from changes in the geometry of the curtain, and main-
taining adequate circulation and separation.
With this method the salt stays at essentially a constant
temperature and is slightly perturbed by control of the external
lead temperature to control power. Study of short-term and
rapid transient behaviocur could not be done with the effort
available but it seems likely that supplementary control would
be needed for this.
Comparison of Fuel Cycle Performance with other FTast Breeder
Reaector Schemnes
In the Table below, the sodium-cooled fast breeder cases
given are considered typical of an oxide-fuelled design and of
possible advanced designs using carbide fuel in the core as
well as blanket. The two gas-cooled fast reactor cases are
taken from recent publications by the Gas Breeder Reactor
Association.
NOT FOR PUBLICATION (COMMERCIATL)
The MAFR doubling times are quoted for 65% Load Factor and
A reprocessing hold-up time of 9 months, with 2% Pu losses to be
comparable Lo the other cases in the preliminary work, doubling
times do not include the plutonium formation for equilibrium
blanket conditions. Although the figures for different systems
are no%t on a strictly comparable basis and the reactor sizes are
different, it is considered the figures can be used to illustrate
the issues adeguately.
TABLE 4.1
Comparison of Performance of Reference
MSFR with other Fast Reactors
Specific
Thermal| Power | System . ) )
Reactor Power Densigy Inventory|Breeding| Doudling
MWt |MWt/m” |Kg Pupsg Gain Time
MWt
1330 MWe TMFRR (Oxide/Carbides| 3100 L84 1.23 0.18 3
Blanket)
1430 MWe LM?3R {(Carbide) 3100 484 1.06 0.33 16
1000 MWe GOFE (¥Vin) 2720 247 1.54 0.45 13
1000 MWe GCFR (Particle) 2840 421 1.31 0.36 17
2500 MWe Tndirectly Cooled 6000 364 1.82% 0.17 4y
MSFR (ClL design 1)
2500 MWe Tndirectly Cooled 6000 364 1.75% 0.29 25
MSFR (0157 Design 1)
¥ Conditions are guoted for the reference design cases with maximun
salt temperatures of 810°C, 20-25% reduction in inventory is
possible if maximum salt temperatures can be increased to 10007C.
/ Use of later data sets with a six batch fuelling cycle gives a
breeding gain of 0.24 and a doubling time of 26 years for the
oxide fuelled IMFBR; this later data has not yet been applied
to the MSHFR cases however.
Tt will he seen that the specific inventory of the molten
salt system is higher than for the other two types, but if Cl-37
is invoked, the improvement in breeding gain means the MSFR can
have a doubling time of about 25 years. Although this is higher
than for the advanced LMFBR and the GCFR with current trends
towards less frequent refuelling the breeding gains of these
reactors would be ilowered and the doubling times would increase.
10
v
NOT FOR PUBLICATION (COMMEKCIAL)
. Safety and Operational Aspects
has only been possible to make a very limited aporaiond
of these aspects and the notes below form a preliminary assess-
ment of the problems.
5.1
Normal Operation
5.1.1 Startup
The circults and the salt supply will first have
to be suitably preheated. The salt, cither without
plutonium or containing a "safe" concentration of
plutonium, can be introduced into the system from the
dump/storage tanks and the former fully flow tested,
etc. Plutonium can then gradually be added through
the on-line clean up loop, for example, until
criticality at zero power and a nominal Temperature
is reached. Further gradual additions of plutonium
will cause the power to rise and by manipulation
of the secondary circuit conditions, full temnera-
ture at low power reached. Drawing heat from the
secondary circuit will then cause the power to rise
to the desired level. The main operational control
will be by the secondary circuit.
5.1.2 Power Control
The strong negative temperature coefficient can
be used for control by temperature adjustment via the
secondary circuit. For very short term (i.e. spinning
reserve ) demands it may be necessary to incorporate
some additional heat capacity in the secondary system
as well as adjusting a by-pass round the steam
generators. In the event of a pump fault, tn: system
woiild reduce power and it may be possible to adjiust
hack to a higher power if some plutonium addition is
permissible; this would clearly not be done as a