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ORNL-CF-57-8-7.txt
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EAS
N AND F
DESIG
OAK RIDGE SCHOQL OF REACTOR TECHNOLOGY 53'77 t%% h
T ims cxorument consist ol 1 9\3 Lo
o 2O of B3 A9pas; &Maaafiimifi
Reactor Design snd Feasibility Study
"HIGH PERFORMANCE MARINE REACTOR"
Prepapred by:
K. H. Dufrane, Group Leader
T. G. Barnes
C. Bicheldinger
W. D. Lee
N. P. Otto
C. P. Patterson
T. G. Proctor
R. W. Thorpe
R. A, Watson
August 1957
26,
28,
29,
30.
31.
32.
33.
34,
36.
37
38.
39.
40 '”ll'l .
A. M. Weinberg
J. A. Swartout
R. A. Charpie
W. H. Jordan
Lewis Nelson
D. C, Hamilton
E. P. Blizard
L. B. Holland
W. B, Kim'ley
W. R. Gall
A. P, Frags
J. A. Lane
P. R. Kasten
A. F. Rupp
E. 8. Bettis
C. E. Winters
R. B. Briggs
A. L., Boch
W. T. Purgerson
R. V. Meghreblian
L. R. Dresner
K. H. Dufrane
T. G. Barnes
C. Eicheldinger
W. D. Lee
N. P. Otto
C. P. Patterson
T. G. Proctor
R. W. 'I'hOl’pe
- A, Watson
ho-h3, REmp Library
4hohs.
4666,
O7-72. ORSORT Files
73-87. TIsE
88.
P. P. Eddy, Maritime Reac
Martin Skinner
Central Research Library
Laboratory Records
PREFACE
In Septenber, 1956, a group of men experienced in various scientific
and engineering flelds embarked on the twelve months of study which culmi-
nated in this report. For nine of those months, formal classroom and
student laboratory work occupled their time. AT the end of that period,
these nine students were presented with a problem in reactor design. They
studied it for ten weeks, the final period of the school term.
This is a summsry report of their effort. It must be realized that,
in so short s time, a sgtudy of this scope can not be gusranteed complete
or free of error. This "thesis" is not offered as a polished engineering
report, but rather as & record of the work done by the group under the
leadership of the group leader. It is issued for use by those persons
competent to assess the uncertainties inherent in the results obtained in
terms of the preciseness of the technical data and analytical methods
employed in the study. In the opinion of the students and faculty of
ORSORT, the problem.has served the pedagogical purpose for which it was
intended.
The faculty Joins the authors in an expression of appreciation for
the generous assistance which various members of the QOak Ridge National
Laboratory gave. In particular, the guidance of the group consultant,
A. P. Frags, is gratefully acknowledged.
Lewis Nelson
for
The Faculty of ORSORT
W,
ABSTRACT
For marine applications & circulating fuel, fused fluoride salt reactor
gsysten appears to qffer'a sfibStantially reduced specific weight (1bs per shaft
horsepower) ovér'current and planned reactor systems, Such a weight reduction
would make nuclear power'feasible.forfsurface ships smaller than 7500 tons
displacement, the cufrent_mifiifiufi for.pfesent and proposed reactor systems,
as well as overall performance improvements for larger vegsels,
Keeping within the bounds of currently available technology and proven
practices, reactor-steam system capsble of developing 35,000 SHP with an
overall specific weight of approximately 6.4 1bs/SHP is indicated, The
partieulaf installation of this sysiem aboard a 931 class destroyer of 3-4000
tons displacement was found feasible, When this system is used in conjunction
with the.conventional steam systenm to provide‘fuel—oil for shielding, an
overall reactof plant weight of 5/ lbs/SHP is realized,
In addition, the future potential of this design concept was investipated
utilizing unproven but indicated feasibie teéhnology advancements, Speéific
weights on the or&er.of 54 1bg/SHP were ‘found possible in this power range;
ACKNOWLEDGEMENT
The sauthors wish to take this opportunity to express their appreciation
to the many people throughout Osk Ridge National Laboratory who so_freely
allowed us to infringe upbn their spare moments to gain the benefits of
their experiences and knoyledge.
The group's special thanks goes to A, P, Fraas and W. R, Chambers,
our group advisors, for their guldance and for selecting the study. Our
particular indebtedness to the many pecople of the ANP Project‘at ORNL is
attested by our numerous. references to their work.
Also we wish to acknowledge the personal aid received from specialists
v of the Bethlehem Steel Shipbuilding Division, Ingalls Shipbuilding Company,
Babcock and Wileox, and the Knolls Atomic Power Laboratory.
-6-
TABLE OF CONTENTS-
1.0 Summary, Descrifition and Conclusion
2.0
3.0
1.1
1.2
1.3
1.4
1.5
1.6
1.7
Introduction
Réactor
Fuel
Materials
Heafi Exchangers and Steam Generators
Potential |
Conclusions
Introduction
2.1
2.2
2.3
2.h
2.5
2.6
Need for a High Performance Marine Reactor
Ship Installation |
Design Philosophy
Reactor Comparison and Selection
Advantages and Dlsadvantages of Fused Salt Reactors
Additional Applications
OveralltPower Plant Description
3.1
3.2
3.3
3.4
3.5
3.6
3.7
. Introduction
Alternate Approsach
Reactor
General
Shielding
Weight Comparison of Nuclear and Conventional System
Hazard Evaluation
Page
15
15
16
18
20
20
21
22
24
2l
25
26
28
30
33
35
35
38
39
43
42
43
b5
L
Page
v 4,0 Fuel and Secondary Fluid W6
4,1 Fuel b6
4.1,1 Introduction hé
4,1.,2 Coupogition Wt
4.1.,3 Corrosion 51
4,1.% Physical and Thermal Properties 53
4,1.5 Nuclear Properties 54
4,1.6 Availability and Cost B
4,1.7 Fuel Addition 55
%g: 4.1.,8 Fuel Reprocessing 55
J k,2 Secondary Fluid 57
4.2.1 Introduction 57
4,2,2 Physical and Thermal Properties 58
4,2.,3 Disadvantages of Fluid 59
5.0 Material Selection 61
5.1 Structural | : 61
5.2 Moderator 65
5.3 Reflector 66
. 5.4 . Poisoned Modetator Section 66
‘ffi 5.5 Design Properties of Materials | 67
¢ 6.0 Reactor and Primary Heat Exchanger Design 68
6.1 Introduction 68
6.2 Reactor - Types Cofisidered and Selection 68
6.2.1 Internal Arrangement 69
6.2;2 Vessel Design 73
6.2.3 Structural Arrangement | 75
7.0
8.0
S~
6.2.4 Fuel Pumps
6.2,5 Pressurizes and Expansion Chamber
6.3 Primary Heat Exchangers
6.3.1 Design Criferia_
6.3.2 Basic Design
6.3.3 Parameter Study
6.3.4 Stress Considerations
Steam Generating System
7.1 Introduction
7.2 Molten Salt Cycle Selection
7.3 Steam Generator
" T.3.1 Types Consgsidered
T.3.2 Design of Selected Steam Generator
7.4 Superheater
7.5 Auxiliary Equipment
7.6 Part Load Operation
Reactor Analysis
8.1 Nuclear Configuration
8.2 Parameter Study
8.2.1 Cross Sections
8.2,2 Summary of Results
8.2.3 Control Rod Study
Page
76
76
78
78
78
83
8k
88
88
88
91
91
ok
97
98
102
110
110
2113
114
116
117
o~
a3
oy v
B
€
9.0
10.0
8.3 Nuclear Design
8.3.1 Criticality
8.3.2 Self Shielding
8.3.3 Burnup and Fisgion Product Poisons
8.3.h Prompt Temperature Coefficients
8.3.5 ZXenon Poison
8.3.6 Delay Neutron Loss
8.3.7 Excess Reactivity Requirements
8.3.8 Control Requirements
Shielding
9.1 Introduction
G.2 Neutron Flux Calculation
9.3 Secondary Salt Activation
9.4 Dose Tolerance levels
9.5 General Shield Arrangemenf
9,6 Primary Shield
9.7 Secondary Shield
Heat Balance and General Aspects of the Steam System
10.1 Introduction
10,2 Steam Requirements
10,3 Condensate and Exhaust Heat
10,4 Heat Addition in the Steam Generating System
10.5 Comparison of Efficiencies
Page
123
124
12k
129
129
131
131
132
133
135
135
135
141
142
143
145
146
154
154
154
157
158
158
w1 0w
Page
11,0 Overall Power Plant Particulars - 160 |
11.1 Introduction | 160 ¥
11,2 General Arrangement - 160
11.3 Power Plant Control | 165
11,4 Emergency Operation 171
11,5 Maintenance 178
11,6 Removal and Disposal of Volatile Fission Products _ 180
11,7 PFuel Loading | . | : * 182
11,8 Pumps, Valves and Blenders | 184
12,0 Modified Approach 189 «
13,0 Weight Summary | 191
14,0 Future Potential | | 196 )
-
Figuré No.
2-1
3-1
3-2
3~3
h-1
b2
4-3
Lok
5-1
5-3
6-1
1]
LIST OF FIGURES
Partial Summary of Current and Proposed Nuclear
Marine Installations
Flow Diagram
Reactor Diagram
Specific Weight Comparison in 1b/shp
Phase Diagram of the Three-Component NaF—Zth-UFh
System
Partial Pressure of ZrF, Based on the Assumption
that Only NaF and ZrF) %xist in the Vapor Phase
Fused Salt Fluoride Volatility Uranium Recovery
Process
The System LiF-NaF-BeF,
Design Curve for As-Received Inconel Tested in
Fused Salt No, 30 at 1300°F|
Comparison of the Stress Rupture Properties of As-
Received Inconel Tested at 1300, 1500 and 1650°F
in Argon and Fused Salt No. 30
Effect of Section Thickness on Creep-Rupture
Properties of As-Recelved Inconel Tested in Fused
Salt No, 30 at 1500°F under 3500 psi Stress
Estimate of Weight Per Power Ratio vs Primary Heat
Exchanger Outer Diameter for Various Tube Spacings
Proposed Steam Generator
Proposed Superhea ter
Proposed Basic Arrangement
Salt Viscosity
Friction Factor
Heat Transfer Correlatlon
Pump Equivalent Weight
Page
29
36
41
by
49
50
56
60
62
63
64
85
103
104
105
106
107
108
109
Figure No,
g1
g-2
8-3
Bl
8-5
8-6
817
8-8
9-14
9-1B
9=2
9=3
10-1
11=1
112
11-3
11-6
11=7
-]2=
Reacfivity vs Mass U=235
Reactivity'vs U~235 Concentration
Reactivity vs U=235 Mass
Radial Flux Distribution
Radial Power Distribution
Thermal Flux Distribution in Unit Lattice Cell
Percent Reactivity loss During Lifetime Due to
Burnup and Fission Product Polsons
Core Reactivity vs Cofitrol Rod Position
Neutron Flux Plot -~ Core té Primary Shield Lead
Neutron Flux Plot in Primary Shield Tank
Secondary Shield
Reactor Compartment
Predicted Steam Balance for Reactor Powered System
at 359,000 shp |
General Arrangement
Simulation Flow Sheet
Reactor Power and Temperature vs Time for a
Ramp, Change in Power Demand
Reactor Power and Temperature vs Time for a Step
Change in Power Demand
Reactor Power and Temperature vs Time for Step
Change in Reactivity
Output Steam Temperature vsg Load
Reactor Power and Steam Temperature vs Time for
a Linear Change in Power Demand
Page
118
119
125
126
127
128
130
134
139
140
144
149
155
163
172
173
17Th
175
176
177
Figure Nog
A<5,1
A=5,2
A=5,3
A=6,1
A=11,1
A"“ll 92
A=11.3
A=11,/
A=11,5
=1 3
InconelhDesign Data
Inconel Degign Data
Inconel Design Data
Moderator Rod Tefiperature Distribution
Analog Represgentation of Fuel Loop
Analog Representation of Salt Side of Primary
Heat Exchanger and Superheater
Analog Representation of Salt Side of Steam
Generator
Method of Generating Power Demand Voltages
Analog Repregentation of Control System
Page
20k
205
206
214
2hg
250
251
I252
253
~14e
APPENDIX Pago i
5el Materials Data ¢« o ¢ o o o o o 0 2 s o o o o o o 202
6.1 Jugtification of Moderator Material . . o . « , 207
6,2 Calculations for Final Design of Primary Heat
Exchanger o« o o s o o 6 06 6 06 6 o 6 0 o 0 0 o o 215
7.1 Steam Generating System o o o o o o o o o o o o 226
8,1 Three=Group Cross Sections. o o o o o o o o o o 2ko
8.2 Perturbation Technique o o o o o o o o o o o o 21
8,3 Burnup and fission Product Poisons . « o « . & 2h3
8.4 Prompt Neutron Lifetime . « o o o o o o o o o o 25 )
11,1 Degceription of Simulation Program o o o o o o 246 .
11,2 BExpansion Chamber Heating Calculations . , . . 248 -
13,1 Breakdown of Basic Reactor Powered System
Components Weigh‘ba © &6 B © & 6 © © B ° o 6 o6 o 255
=15
1,0 SUMMARY, DESCRIPTION AND CONCLUSIONS
1,1 Introduction
This report covefs a study of the feésibility of & high performance
marine reactor (HPMR) utilizing a circulating fuel, fused salt reactor concept.,
The definition of high performance as considered in this report is low
specific velght in terms of total power plant weight per shaft horsepower,
By significantly decreasing specific weight below that which is currently
found feasible with present and proposed systems, reactor installations on
a lighter class of ships is now possible. This wduld also offer potential
improvements for all heavier classes,
A design study was made for a reactor system of this type to power a
931 class destroyer of 3-4000 tons displacgmenta The reactor and steanm
generating equipment simply replaced one of the present boiler rooms on
this c¢lass ship and duplicated the steam conditions (950°F, 1200 psig)
supplied to the propulsion machinery. An overall specific weighi of 59 ibs/SHP
was achieved for the 35,000 SHP delivered per boiler room, This is comparable
with the presently installed oil-fired system including fuel.‘ This speci=
fic weight was achieved with a reactor afid steam generating equipment overdesign
of approximately 30%, Indications are that if time had allowed a reiteration
of the system size to the 10% overdesign factor used in most reactor systems,
a specific weight reduction to at least 54 1lbs/SHP would have been achieved,
These specific weights, which are approximately one half that of any planned
syatem, were brought about by obtaining a small reactor package to minimize
shielding and combining this with the production of high temperature steam
to give godd steam plant efficiency,
=] b
The initial basic study incorporated a single intermediate loop utilizing
gnother fused salt {also compatible with water) to transfer the heat from the
fuel to the steam generator and superheater. This prevented activation of
the steam and through the use of blenders the temperature of the salt entering
the steam generator was feduced substantially to decrease the problem of
" thermal stress, However,; this required that saconflary shielding be placed
about the large volume of fhe steam generating equipment,- It was found that
through the use of two intermediate loops the amount of secondary shielding
could be.redueed and the overall specific weight releaaed from 58 to the 54
1bs/SHP, The comparable reduction fdr the case with 30% overdesign is from
65 to 59 1bs/SHP. Unfortunately sufficient time was not available to allow
as detailed a study as that given to the single intermediate loop systen,
Considerable use and reference has been made of the ANP studies and
experimental work carried out at ORNL on fused salt reactors, This has
allowed demofistrated components and materials to be incorporated directly
into this plant,
1.2 Reagtor
In order to achieve the primary overall objective of reduced specific
weight it is desirable to keep the reactor size as small as possible in order
fio minimize n;t only reactor weight but that of the primary and secondary
éhielding as well, The compact reactor selected was cylindrical in shape with
the fuel circulating up through a central critical region and then down through
an ammular downcomer at its periphery.containing the primary heat exchangers
(fuel to secondary fluid). The core is moderated by cylindriecsgl rods of
beryllium oxide clad with Inconel that are gquisPaced throughout the core region,
A nickel reflector surrounding the core plus an additional blankeflblack to
=] e
thermal neutrons shield the primary heat exchanger and prevents excessive
activation of the secondary fluid,
Because of the inherent stability that has been demonstrated with
reactors of this type, poison rods are not needed for control but a single
réd is placed at the core centerline to provide for reactor shutdown, mean
témpérature change, and fuel burnup, |
The reactor and steam generating system were designed to produce 125 MW
which is a conservative overdesign of greater than 25%., This safety factor
is considerably larger than felt necessary but was brought about by the
necesgity of starting the reactor design before the details of the steanm
_ system became available,
An average core temperature of 1225°F with an 100°F difference across
the core was selected as a compromise of weight and thermal efficiency against
corrosion and thermal stress problems,
The neutron flux gpectrum is largely intermediate giving rise to a
fission distribution of 28% thermal, 63% intermediate and 9% fast,
~ The nickel reflector tends to hold up the thermal flux spectrum at the
outer edge of the core and helps %o prpvide the favorable pesk to average
power diétribution of approximately 1.4. The power density averaged over
the core is 360 watts/cmB. |
The reactor vessel itself is approximately 6,7 ft in diameter and 6,7
ft high.’ An expansion tank for the fuel is incorporated into the head design
along with provisions for removing Xenon and other fission product gases., Three
fuel pumps are also located in the reacfor head in a manner such that they may
be replaced aboard ship. The reactor head is removable by unbolting and cutting
a smell omega type seal weld, This allows replacement of the primary heat
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exchangers afid inspection of the core agsembly, However, it is recomménded
that the reactor be removed from the ship prior to this operation in order
to reduce the remote hgndling costs and problems., Also the feasibility
of balancing the cost of discarding complete reactor assemblies against that
of the design and operation of a remofe handling facility should be thoroughly
investigated with the idea of reducing both overall costs and simplification
of the basic reactor design,
The primary reactor shield is made up of structural support steel along
with approximately 5 inches of lead and 39 inches of water, The shield
requirements are based mainly on the fission product and sodium decay gamma's
and the delay and fission neutrons in the outer annular region containing
the primary heat exchangers. These activities were found to be seversl
order of magnitudes greaterAthan the prompt gamma and neutron radiation from
the core,
The secondar; shield for the basic_study enveloped both the reactor énd
the steam generating equipment and incorporated a thickness ofJapproximately
4 = 6=1/2 inches of lead. This requirement is a direet function of the
activation ‘of the sodium ions in the secondary fluid as it passes through
the primary heat exchangers.
1.3 Fuel and Secondary Fluid
In the selection of a fuel for this system, in addition to simpiy
selecting a carrier for a critical amount of uranium, primary emphasis was
placed on chdosing one that had been proven acceptable, This included its
chem;cal stability, corrosion, nuclear, and physical properties. This selection
was rather easily made since a large number of salts have been investigated
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by ORNL and only a few found promising enough to warrant additional testing,
A solution of sodium, zirconium and uranium fluorides was selected on
the basis of reasonable nuclear and physical properties and because it had
been used successfully in a reactor experiment (ARE)}, Also, extensive
investigations have been made on its corrosion and physical properties in
anticipation of its use in the Aireraft Reactor Test (ART), The vapor
pressure of this salt is typically very low so that at operating temperatures
the reactor vessel has to be pressurized only slightly to prevent pump
cavitation, Thé actual composition of the fuel selected; closely approximating
that of the ART except for exact uranium concentration, is 9% NaF, 453 23
and 6% UFA (mole percent),
Uranium will be added to the system in the form of (NaF), UF,, Pellots
4°
or dissolved golution of this salt would be added during operation of the
reactor to compensate for uranium burn-up and to override fission product
and corrosion poisons. It is anticipated that sufficient addition of fuel
may be made throughout the life of the reactor to eliminate the necessity
of rgplacing the original salfi loading.
A basic ground rule requiring chemical aompatabiiity of the fuel, sécondary
fluid, water and sea water was established. In view of this coupled with
corrosion, heat transfer, radiation and chemical stability requirements, the
selection of possible choices was narrowed down to a fused salt, Because of
the difficulties involved in preventing this salt from freezing in the steam
gonerator a low melting point was also a requirement, On this besis a solution
of sodium, lithium, beryllium fluorides (mole percentages of 30, 20 and 50%